Название |
Laser welding of new austenitic cryogenic corrosion-resistant steels alloyed with nitrogen |
Информация об авторе |
National University of Science and Technology “MISiS” (Moscow, Russia) L. M. Kaputkina, Dr. Phys.-Math., Prof., Chief Researcher, Metal Forming Dept., e-mail: kaputkina@mail.ru D. E. Kaputkin, Dr. Eng., Associate Prof., Dept. of Physics; I. V. Smarygina, Cand. Eng., Associate Prof., Metal Forming Dept.
Moscow State Technical University of Civil Aviation (Moscow, Russia): V. E. Kindop, Cand. Eng., Senior Researcher, Deputy Head of Science Directorate |
Реферат |
There were studied structures and properties of welded joints of laboratory melted austenitic steels: Fe-0.04C-18Cr-9Ni-0.2N and new-developed Fe-0.1C-19Cr-10Mn-6Ni-0.3N-2Mo and Fe-0.1C-19Cr-10Mn-6Ni-0.3N-2Mo-2Cu. Correct choice of composition and deformation-heat treatment leads the new-developed steels are high-strength corrosion-resistant ones with stable austenite. Computer simulation shows that enough quality of welded seam can be provided by laser welding of plates of up to 4 mm in thick at the room temperature. For bigger thicknesses preliminary heating is necessary. Microstructure, phase compositions, lattice periods, X-ray diffraction peak broadening, microhardness, bending strength and ductility, resistance against intercrystalline, pitting and total corrosion was studied for bulk metal and laser welded joints of high-temperature thermomechanically treated hot-rolled plates, including tests after 1000 thermal cycles in range –163…+20 °C were investigated. It was shown that welded seams are 300…1000 μm in wide and have no porosity and no thermal affected zone. The welded seam strength is the same as for bulk metal, 180° bend test shows no cracks in the seam. The resistances of welded seam and bulk of Fe-0.1C-19Cr-10Mn-6Ni-0.3N-2Mo and Fe-0.1C-19Cr-10Mn-6Ni-0.3N-2Mo-2Cu steels against total corrosion in the sea water (3 % NaCl) and in acid environment (0,5M H2SO4, including additional blowdown by H2S), pitting and intercrystalline corrosion in standard environments are practically equal. The structures, phase compositions, hardnesses and corrosion resistances of welded joints of both new-developed steels are constant after the thermocycling. |
Библиографический список |
1. Speidel M. O. Nitrogen Containing Austenitic Stainless Steels. Mat-wiss. u. Werkstoiftech. 2006. Vol. 37, Iss. 10. pp. 875–880. 2. Berns H., Gavriljuk V., Riedner S. High interstitial stainless austenitic steels. Berlin: Springer, 2013. 169 p. 3. Naumenko V. V., Shlyamnev А. P., Filippov Филиппов G. А. Nitrogen in austenitic stainless steels of various alloying systems. Metallurg. 2011. No. 6. pp. 46–53. 4. Gorynin I. V., Malyshevskiy V. А., Kalinin G. Yu., Mushnikova S. Yu., Bannykh О. А., Blinov V. М., Kostina М. V. Corrosion-resistant high-strength nitrogenous steels. Voprosy materialovedeniya. 2009. No.3 (59). pp. 7–16. 5. Saenarjhan N., Kang J.-H., Kim S.-J. Effects of carbon and nitrogen on austenite stability and tensile deformation behavior of 15Cr-15Mn-4Ni based austenitic stainless steels. Materials Science and Engineering A. 2019. Vol. 742. pp. 608–616. 6. Herrera C., Seifert M., Niederhofer P. Development of a new high interstitial non-magnetic stainless steel for oil and gas applications. NACE - International Corrosion Conference Series. 2020. Vol. 2020. 162081. 7. Baba H., Kodama T., Katada Y. Role of nitrogen the corrosion behavior of austenitic stainless steels. Corrosion Science. 2002. Vol. 44. pp. 2393–2407. 8. Mushnikova S. Yu., Legostaev Yu. L., Kharkov А. А., Petrov S. N., Kalinin G. Yu. Study of nitrogen effect on pitting corrosion resistance of austenitic steels. Voprosy materialovedeniya. 2004. No. 2 (38). pp. 126–135. 9. Poonguzhali A., Pujar M. G., Mudali U. K. Effect of nitrogen and sensitization on the microstructure and pitting corrosion behavior of AISI type 316LN stainless steels. Journal of Materials Engineering and Performance. 2013. Vol. 22, Iss. 4. pp. 1170–1178. 10. Kernion S. J., Werley T. N. A comparison of corrosion resistant, high N austenitic stainless steels. NACE - International Corrosion Conference Series. 2017. Vol. 4. pp. 2713–2721. 11. Shiganov I. N., Kuryntsev S. V. Modern trends in laser welding (Review. Part 1). Naukoemkie tekhnologii v mashinostroenii. 2015. No. 6. pp. 35–42. 12. Ignatov А. G. Laser welding: history, state and prospects. Ritm mashinostroeniya. 2019. No. 8. pp. 24–36. 13. Ignatov А. G., Krivorotov V. I., Mirgorodskiy V. А. Laser welded joints made of corrosion-resistant steels. Fotonika. 2010. No. 2. pp. 18–21. 14. Grigoryants А. G., Misyurov А. I., Shiganov I. N., Perestoronin А. V. Properties of laser welded joints of cryogenic austenitic nitrogen-containing steel. Svarochnoe proizvodstvo. 2020. No. 7. pp. 22–27. 15. Woo I., Kikuchi Y. Weldability of high nitrogen stainless steel. ISIJ International. 2002. Vol. 42, Iss. 12. pp. 1334–1343. 16. Mohammed R., Madhusudhan Reddy G., Srinivasa Rao K. Welding of nickel free high nitrogen stainless steel: Microstructure and mechanical properties. Defence Technology. 2017. Vol. 13, Iss. 2. pp. 59–71. 17. Cheng M., He P., Lei L., Tan X., Wang X., Sun Y. Li J., Jiang Y. Comparative studies on microstructure evolution and corrosion resistance of 304 and a newly developed high Mn and N austenitic stainless steel welded joints. Corrosion Science. 2021. Vol. 183. pp. 109338. 18. Iamboliev T., Zumbilev A., Christov S., Kalev L., Ianev V., Stang R. G. Laser beam welding of high-nitrogen-containing austenitic stainless steel. Welding Journal. 1999. Vol. 78, Iss. 7. pp. 245–252. 19. Zhao L., Tian Z., Peng Y. Porosity and nitrogen content of weld metal in laser welding of high nitrogen austenitic stainless steel. ISIJ International. 2007. Vol. 47, Iss. 12. pp. 1772–1775. 20. Norris J. T., Robino C. V., Hirschfeld D. A., Perricone M. J. Effects of laser parameters on porosity formation: Investigating millimeter scale continous wave Nd: YAG laser welds. Welding Journal. 2011. Vol. 90, Iss. 10. pp. 198–203. 21. Kostina V. S., Kostina М. V., Voronchuk S. D., Muradyan S. О., Rigina L. G. Study of structure and properties of metal of welded joints obtained by laser welding of austenitic steel with ~ 0.5% N in the cast and deformed state. Metally. 2018. No. 5. pp. 3–11. 22. Grigoryants A.G., Shiganov I. N., Starozhuk E. A., et. al. High-strength cryogenic austenite weldable structural steel and steel obtainment method. Patent RF, No. 2545856. Applied: 02.08.2013. Published: 10.04.2015. 23. Filonov M. R., Bazhenov V. E., Glebov A. G., et. al. Structural cryogenic austenite high-strength corrosion-resistant, including bioactive media, welded steel and method of processing. Patent RF, No. 2584315. Applied: 04.06.2015. Published: 20.05.2016. 24. Kaputkina L. M., Svyazhin A. G, Smarygina I. V., Kindop V. E. Influence of nitrogen and copper on hardening of austenitic chromium-nickelmanganese stainless steel. CIS Iron and Steel Review. 2016. Vol. 11. pp. 30–34. 25. Kaputkina L. М., Smarygina I. V., Svyazhin А. G., Kindop V. E., Blinov Е. V. Stability of the structure and properties of nitrogenous high-strength austenitic steels under cyclic thermal and mechanical loads. Metallovedenie i termicheskaya obrabotka metallov. 2019. No.1 (763). pp. 3–9. 26. Kaputkina L. M., Svyazhin A. G, Smarygina I. V., Bobkov T. V. Corrosion resistance in various environments of high-strength austenitic nitrogen chromium-nickel-manganese steel. Izvestiya vuzov. Chernaya metallurgiya. 2016. Vol. 59. No. 9. pp. 663–670. 27. GOST 11150–84. Metals. Methods of tension tests at low temperatures. Introduced: 01.01.1986. 28. GOST 1497–84. Metals. Methods of tension test. Introduced: 01.01.1986. 29. GOST 6996–66. Welded joints. Methods of mechanical properties determination. Introduced: 01.01.1967. 30. GOST 9.914–91. Unified system of corrosion and ageing protection. Corrosion-resistant austenitic steels. Introduced: 01.01.1992. 31. GOST 9.912–89. Unified system of corrosion and ageing protection. Corrosion-resistant steels and alloys. Introduced: 01.01.1991. 32. Ushakov I. V., Batomunkuev А. Yu. Computer simulation of the specifics of heating during laser double-sided welding of Kh19N6G9AM2 steel. Vestnik Tambovskogo gosudarstvennogo tekhnicheskogo universiteta. 2016. Vol. 22. No. 3. pp. 491–500. |