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Production of Pipes
ArticleName Brief description of methods for assessing the compatibility of steels with hydrogen and test results of X52 and X70 LDP
DOI 10.17580/chm.2024.02.06
ArticleAuthor N. A. Devyaterikova, K. A. Laev, A. S. Tsvetkov, S. E. Dagaev
ArticleAuthorData

PAO "TMK", Pervouralsk, Russia

N. A. Devyaterikova, Chief Specialist, Center for Industrial Pipes, e-mail: n.devyaterikova@tmk-group.com
K. A. Laev, Cand. Eng., Chief Specialist, Center for Industrial Pipe

 

Peter the Great St. Petersburg Polytechnic University, St. Petersburg, Russia
A. S. Tsvetkov, Cand. Eng., Head of the Testing Laboratory of the Scientific and Technological Complex “New Technologies and Materials” of the Advanced Engineering School “Digital Engineering”
S. E. Dagaev, Engineer of the Testing Laboratory of the Scientific and Technological Complex “New Technologies and Materials” of the Advanced Engineering School “Digital Engineering”

Abstract

To assess the suitability of welded pipes for hydrogen transportation, pipe steel of grades X52 and X70 (manufactured by TMK), which are widely used for main gas pipelines, were examined. Tests in hydrogen gas at 10 MPa included tensile test at a slow strain rate and determination of the level of threshold stress intensity factor (KIH), and a disk fracture test with gradually increasing hydrogen pressure was also performed. Besides base material, submerged arc welds have been tested. Three types of complementary tests provided the most complete picture of the effect of hydrogen on the properties of steels: change in plastic properties (SSRT), evaluation of resistance to crack development (KIH determination), and change in strength properties (disk test). According to SSRT test results, X52 and X70 show a trend of moderate ductility reduction but high resistance to crack development in hydrogen environment: all obtained KIH values for base metal, weld metal and heat-affected zone are above the requirements of ASME B 31.12. Disk tests indicate that hydrogen embrittlement is only possible with long-term exposure. In general, the investigated steels X52, X70 on the totality of the obtained test results show satisfactory resistance to the action of gaseous hydrogen as the base metal and welded joint, which indicates the possibility of using Russian-made pipes for hydrogen transportation.
The work was attended by A. G. Nikolaeva, engineer of the Testing Laboratory of STC “New Technologies and Materials”, AES “Digital Engineering”, Federal State Autonomous Educational Institution of Higher Education “SPbPU”.
The research was carried out at the Federal State Autonomous Educational Institution of Higher Education "SPbPU".
The research was carried out by PAO TMK and Peter the Great St. Petersburg Polytechnic University with partial financial support from the Ministry of Science and Higher Education of the Russian Federation as part of the program of the World-Class Scientific Center: Advanced Digital Technologies (contract No. 075-15-2022-311 dated April 20, 2022).

keywords Hydrogen transport pipes, pipeline steel, hydrogen embrittlement, X52, X70, slow strain rate tensile test, stress intensity factor, disk pressure test
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