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PROCESSING AND COMPLEX USAGE OF MINERAL RAW MATERIALS
Название Role and effect of in-situ leach uranium oxidizers in by-recovery of rhenium
DOI 10.17580/gzh.2018.09.11
Автор Vasilenok O. P., Ruziev B. T., Ivanova I. A.
Информация об авторе

Navoi Mining and Metallurgical Combinat, Navoi, Uzbekistan:

O. P. Vasilenok, Head of the Central Research Laboratory, vasilyonok@ngmk.uz
B. T. Ruziev Head of Uranium Geotechnology Facility of the Central Research Laboratory
I. A. Ivanova, Leading Production Engineer of the Uranium Geotechnology Facility of the Central Research Laboratory

Реферат

This study is devoted to the effect of an oxidizer used in in-situ leaching of uranium on the behavior of an associated useful component – rhenium. The relevance of the study consists in the systematization of influence exerted by various oxidizing agents involved in in-situ leaching of uranium on the rate of rhenium transition to pregnant solution. As a result, it is possible to outline conditions for commercial recovery of rhenium. This work is important as it expands the research with a view to by-recovering scandium, vanadium and other valuable components from complex ore. The authors show that the most significant part in transition of rhenium to leach solution belongs to an oxidizer and its nature. This fact is confirmed by the studies of uranium and rhenium leaching at some deposits in the Tian Shan megaprovince. It is emphasized that without an oxidizer in a sulfurous medium, rhenium transition to pregnant solution to be processed by sorption is under 20–30% while with an oxidizer, rhenium transition exceeds 50–60%. The nature of an oxidizing agent is very important. The most active agents commercially applicable are identifi ed as hydrogen peroxide and sodium hypochlorite.

Ключевые слова Rhenium geochemistry, migration ability, oxidizing medium, localization features, geotechnological mode, leaching, oxidizer, leaching rate
Библиографический список

1. Kushakova L. B., Shumskiy V. A., Brailko O. Yu. Possibility of extraction of secondary constituents during non-ferrous metal ore processing. Tsvetnye Metally. 2016. No. 9. pp. 28–34. DOI: 10.17580/tsm.2016.09.03
2. Kindyakov P. S., Korshunov B. G., Fedorov P. I., Kislyakov I. P., Chemistry and Technology of Rare and Dissiminated Metals. In three volumes. 2nd enlarged and revised edition. Moscow : Vysshaya shkola, 1978. Vol. 3. 320 p.
3. Palant A. A., Troshkina I. D., Chekmarev A. M. Metallurgy of rhenium. Moscow : Nauka, 2007. 298 p.
4. Nway Shwan O. O., Troshkina I. D., Aye Min, Shilyaev A. V. Sorption of rhenium and vanadium from mineralized solutions by fibrous ionites. Russian Journal of Non-Ferrous Metals. 2014. Vol. 55, Iss. 3. pp. 242–246.
5. Zagorodnyaya A. N., Abisheva Z. S., Sadykanova S. E., Sharipova A. S. Sorption of rhenium and uranium from solutions of their joint presence by weakly basic anion exchanger A170. Tsvetnye Metally. 2014. No. 5. pp. 53–60.
6. Palant A. A., Troshkina I. D., Chekmarev A. M., Kostylev A. I. Rhenium technology. Moscow : LLC “Galleya-print”, 2015. 329 p.
7. Trefilova I.V., Degtev M. I., Alikina E. N., Aminjanov A. A. Chemistry, determination and concentration methods of rhenium (VII). Bulletin of Perm University. Chemistry. 2015. No. 1. pp. 66–80.
8. Petrov G. V., Boduen A. Ya., Ivanov B. S., Serebryakov M. A. Investigation of ammonia autoclave leaching of silver and rhenium containing ill-conditioned copper concentrate. Tsvetnye Metally. 2016. No. 10. pp. 23–28. DOI: 10.17580/tsm.2016.10.03
9. Troshkina I. D., Veselova O. A., Vatsura F. Ya., Zakharyan S. V., Serikbay A. U. Sorption of Rhenium from Sulfuric Acid Solutions with Trialkylamine-Containing Impregnates. Russian Journal of Non-Ferrous Metals. 2017. Vol. 58, Iss. 6. pp. 608–613.
10. Panova E. N., Ydrysov A. D. Organization and implementation technology for scaled-up testing of rhenium by-recovery from uranium ore. Nauchnoe znanie sovremennosti. 2018. No. 1. pp. 23–24.
11. Wanees S. A., Daher A. M., Haroun Y. S. A., Gouda M. M., Abdulla A. M., Ali A. H. Leaching, purification and extraction of uranium from salcrete deposits – Egypt. Chemical Technology : An Indian Journal. 2013. Vol. 8, Iss. 2. pp. 46–56.
12. Zakrzewska-Koltuniewicz G., Herdzik-Koniecko I., Cojocaru C., Chajduk E. Experimental design and optimization of leaching process for recovery of valuable chemical elements (U, La, V, Mo, Yb and Th) from low-grade uranium ore. Journal of Hazardous Materials. 2014. Vol. 275. pp. 136–145.
13. Renard S., Sterpenich J., Pironon J., Chiquet P., Randi A. Geochemical effects of an oxycombustion stream containing SO2 and O2 on carbonate rocks in the context of CO2 storage. Chemical Geology. 2014. Vol. 382. pp. 140–152.
14. Karagiorgakis A. L., Schindler M., Spiers G. A. Retention of rare earth elements in authigenic phases following biogeochemical dissolution of ore from Elliot Lake, Ontario. Hydrometallurgy. 2018. Vol. 177. pp. 9–20.

Полный текст статьи Role and effect of in-situ leach uranium oxidizers in by-recovery of rhenium
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