Журналы →  Gornyi Zhurnal →  2020 →  №9 →  Назад

ECONOMY, ORGANIZATION AND MANAGEMENT
Название Valuation of rare earth elements in ore deposits in the Murmansk Region
DOI 10.17580/gzh.2020.09.05
Автор Kalashnikov A. O., Konopleva N. G., Ivanyuk G. Yu.
Информация об авторе

Geological Institute, Kola Science Center, Russian Academy of Sciences, Apatity, Russia:

A. O. Kalashnikov, Senior Researcher, Candidate of Geological and Mineralogical Sciences, kalashnikov@geoksc.apatity.ru
N. G. Konopleva, Senior Researcher, Candidate of Geological and Mineralogical Sciences
G. Yu. Ivanyuk, Doctor of Geological and Mineralogical Sciences

Реферат

The Kola rare-earth metallogenic province is the biggest in Russia. The largest resources of rare earth elements (REE) are confined to the Khibiny apatite deposits and loparite and eudialyte deposits of the Lovozero massif. In order to compare the prospects of different Kola deposits and occurrences, we estimated the value of rare-earth oxides contained in ores pursuant to average market prices of certain rare-earth oxides. Heavy REE (Dy, Yb, Tm, Tb, Lu) and Nd make the largest contribution to the value of REE-bearing ores despite the fact that light REE (La and Ce) make up the majority of the REE resources of almost all deposits in the region. Given the variety of mineral processing technologies and infrastructure available, we have identified the most important objectives to advance the REE industry in the region: (1) REE recovery from the currently produced minerals, namely, apatite of the Khibiny deposits and baddeleyite of the Kovdor deposit—high-level processing of the Kovdor baddeleyite concentrate can make Russia a dominant player on scandium market; (2) launching mining operations in the multicomponent (Ti-Ta-Nb)-REE-Zr Lovozero eudialyte deposit (in the first place, the Alluaiv site); (3) revaluation of the Afrikanda deposit in the light of new technologies for processing perovskite–titanomagnetite ores, as well as due to the fact that Russia currently lacks domestic production of titanium raw materials; (4) prospecting and exploration of the Keivy occurrences in alkaline granites and pegmatites and the development of processing technologies for these complex ores. The study has been accomplished in the framework of R&D project of the Mining Institute, Kola Science Center, Russian Academy of Sciences, and is partly supported by the Russian Foundation for
Basic Research, Grant No. 12-05-98802. The article is based on the analytical note on request of the Accounting Chamber of the Russian Federation in 2015.

Ключевые слова Rare earth elements, lanthanoids, scandium, Kola rare earth province, apatite, eudialyte, baddeleyite, mineral resources
Библиографический список

1. Connelly N. G., Damhus T., Hartshorn R. M., Hutton A. T. Nomenclature of Inorganic Chemistry : IUPAC Recommendations 2005. London : RSC Publishing, 2005. 366 p.
2. Chakhmouradian A. R., Smith M. P., Kynicky J. From “strategic” tungsten to “green ” neodymium: A century of critical metals at a glance. Ore Geology Reviews. 2015. Vol. 64. pp. 455–458.
3. Koltsov V. Yu., Zakharov А. А., Vlasova T. V., Velichkina N. S. Production of rare earth concentrate from phosphogypsum by heap leaching. Tsvetnye Metally. 2020. No. 2. pp. 56–61. DOI: 10.17580/tsm.2020.02.07
4. Yurasova O. V., Kharlamova T. A., Gasanov A. A., Vasilenko S. A. Technology of cerium (IV) oxide extraction from rare-earth metal concentrates using electrochemical oxidation and extraction methods. Tsvetnye Metally. 2016. No. 3. pp. 42–49. DOI: 10.17580/tsm.2016.03.07
5. Kalashnikov A. O., Konopleva N. G., Pakhomovsky Ya. A., Ivanyuk G. Yu. Rare Earth Deposits of the Murmansk Region, Russia – A Review. Economic Geology. 2016. Vol. 111, No. 7. pp. 1529–1559.
6. Yakovenchuk V. N., Ivanyuk G. Yu., Pakhomovsky Ya. A., Menshikov Yu. P. Khibiny. Laplandia Minerals. Apatity : Laplandia Minerals Ltd., 2005. 463 p.
7. Sarapää O., Al Ani T., Lahti S. I., Lauri L. S., Sarala P. et al. Rare earth exploration potential in Finland. Journal of Geochemical Exploration. 2013. Vol. 133. pp. 25–41.
8. Ogata T., Narita H., Tanaka M., Hoshino M., Kon Y., Watanabe Y. Selective recovery of heavy rare earth elements from apatite with an adsorbent bearing immobilized tridentate amido ligands. Separation and Purification Technology. 2016. Vol. 159. pp. 157–160.
9. Chakhmouradian A. R., Zaitsev A. N. Rare Earth Mineralization in Igneous Rocks: Sources and Processes. Elements. 2012. Vol. 8, No. 5. pp. 347–353.
10. Ihlen P. M., Schiellerup H., Gautneb H., Skår Ø. Characterization of apatite resources in Norway and their REE potential – A review. Ore Geology Reviews. 2014. Vol. 58. pp. 126–147.
11. Osmak A. V., Nikolaeva I. I., Gorshkova N. V. Method of processing rare-earth elements concentrate. Patent RF, No. 2595672. Applied: 16.06.2015. Published: 27.08.2016. Bulletin No. 24.
12. Nikolaev A. I., Larichkin F. D., Gerasimova L. G., Nikolaeva O. A. The Kola peninsula as the titanium province of Russia. Prospects for its utilization. Titan. 2009. No. 3(25). pp. 12–20.
13. Kalashnikov A. O., Yakovenchuk V. N., Pakhomovsky Ya. A., Bazai A. V., Sokharev V. A. et al. Scandium of the Kovdor baddeleyite–apatite–magnetite deposit (Murmansk Region, Russia): Mineralogy, spatial distribution, and potential resource. Ore Geology Reviews. 2016. Vol. 72. pp. 532–537.
14. Lebedev V. N. Extraction and purification of scandium in baddeleyite concentrate treatment. Khimicheskaya tekhnologiya. 2007. Vol. 8, No. 1. pp. 33–37.
15. Lebedev V. N., Lokshin E. P., Melnik N. A., Shchur T. E., Popova L. A. Possibility of Integrated Processing of the Baddeleyite Concentrate. Russian Journal of Applied Chemistry. 2004. Vol. 77, No. 5. pp. 708–710.
16. Lebedev V. N., Lokshin E. P. Niobium and tantalum recovery from baddeleyite concentration tailings. Khimicheskaya tekhnologiya. 2008. Vol. 9, No. 12. pp. 651–654.
17. Nikolaev A. I., Kalinnikov V. T. By-product manufacturing of rare-earth metals during the processing of perovskite concentrate of the Afrikanda deposit. Tsvetnye Metally. 2013. No. 3. pp. 64–69.
18. About the state and use of mineral resources of Russian Federation in 2016 and 2017 : state report. Moscow : LLC Mineral-Info, 2018. 372 p.
19. Davris P., Stopic S., Balomenos E., Panias D., Paspaliaris I., Friedrich B. Leaching of rare earth elements from eudialyte concentrate by suppressing silica gel formation. Minerals Engineering. 2017. Vol. 108. pp. 115–122.
20. Mariano A. N., Mariano A. Rare Earth Mining and Exploration in North America. Elements. 2012. Vol. 8, No. 5. pp. 369–376.
21. Samonov A. E. Prospects for production and use of rare earths in Russia. Typomorphic Minerals and Associations as Size and Quality Indicators of Natural and Manmade Deposits: All-Russian Conference—Annual Meeting of the Russian Mineralogical Society. Yekaterinburg : IGG UrO RAN, 2008. pp. 134–138.
22. Lebedev V. N. Sulfuric Acid Technology for Processing of Eudialyte Concentrate. Russian Journal of Applied Chemistry. 2003. Vol. 76, No. 10. pp. 1559–1563.
23. Mikhailova J. A., Pakhomovsky Ya. A., Ivanyuk G. Yu., Bazai A. V., Yakovenchuk V. N. et al. REE mineralogy and geochemistry of the Western Keivy peralkaline granite massif, Kola Peninsula, Russia. Ore Geology Reviews. 2017. Vol. 82. pp. 181–197.
24. Kalinnikov V. T., Nikolaev A. I., Gerasimova L. G. Kola chemical technology cluster to solve ecological and economical problems in Russia’s Arctic. Sever i rynok: formirovanie ekonomicheskogo porydka. 2014. No. 3(40). pp. 27–31.

Полный текст статьи Valuation of rare earth elements in ore deposits in the Murmansk Region
Назад