Журналы →  Non-ferrous Metals →  2022 →  №1 →  Назад

MATERIALS SCIENCE
Название Refractory materials of metallurgical furnaces with the addition of silicon production waste
DOI 10.17580/nfm.2022.01.05
Автор Bazhin V. Yu., Glazev M. V.
Информация об авторе

Saint-Petersburg Mining University, Saint-Petersburg, Russia:

V. Yu. Bazhin, Doctor of Technical Sciences, Head of Automation of Technological Processes and Production Department, e-mail: bazhin-alfoil@mail.ru
M. V. Glazev, Postgraduate Student of the Department of Metallurgy, e-mail: max77741@gmail.com

Реферат

Currently, there are problems with the operation of metallurgical furnaces at high process temperatures. In the melting zone, the destruction of the side lining and the hearth slab lining in the contact zone of the melt is especially common due to the chemical aggressive environment from the processes of interaction and reactions between the components and mechanical wear as a result of the impact of the tool during maintenance. In most cases, refractory materials do not provide stable operation of the metallurgical unit, they have low operational characteristics. Of scientific and technical interest is the use as a modifying additive for a refractory mixture of technogenic microsilica — waste in the production of metallurgical silicon. Microsilica is a unique finely dispersed composite material with high strength, low density, and with a highly developed particle surface, which further gives refractory products improved strength and durability properties. As part of the study, a series of experiments were conducted with microsilica waste in the production technology of general-purpose fireclay products, as well as in the production technology of refractory concrete mix for monolithic concrete linings and the manufacture of refractory products. It has been established that the optimal value of the content of microsilica in the total mass of general-purpose fireclay products is in the range from 3 to 7%, and in the composition of a dry refractory concrete mixture from 1 to 2%, which does not lead to a decrease in the quality characteristics of the products. Tests of samples have shown that the use of microsilica in the production of refractories can significantly improve properties such as heat resistance and fire resistance, while reducing the cost of production. The obtained results of experiments conducted with the initial microsilica and its behavior in refractory mixtures indicate that the proposed fine composite material can be used in refractory products and introduced into technical standards.

Ключевые слова Refractory material, technogenic microsilica, metallurgical furnace, porosity, strength, refractory resistance, refractory mixture
Библиографический список

1. Chistyakov D. G., Golubev V. O., Sizyakov V. M., Brichkin V. N. Raw Material Composition at Rusal Achinsk and its Impact on the Production Indicators. Tsvetnye Metally. 2020. No. 10. pp. 27–34. DOI: 10.17580/tsm.2020.10.04
2. Brichkin V. N., Vasiliev V. V., Bormotov I. S., Maksimova R. I. Production and Recycling of Limes in Integrated Mineral Processing. Gornyi Zhurnal. 2021. No. 11. pp. 88–94. DOI: 10.17580/gzh.2021.11.12
3. Pyagay I. N., Kremcheev E. A., Pasechnik L. A., Yatsenko S. P. Carbonization Processing of Bauxite Residue as an Alternative Rare Metal Recovery Process. Tsvetnye Metally. 2020. No. 10. pp. 56–63. DOI: 10.17580/tsm.2020.10.08
4. Evseev N. V., Tyutrin A. A., Pastukhov M. P. Granulation of Silicon Production Dust Waste for Return to the Technological Process. Proceedings of Irkutsk State Technical University. 2019. Vol. 23, Iss. 4. pp. 805–815.
5. Tyutrin A. A., Nemchinova N. V. Recycling of Silicon and Ferrosilicon Production Dust. Prospects for the Development of Metallurgy and Mechanical Engineering Using Completed Fundamental Research: Ferroalloys: Proceedings of the Scientific and Practical Conference International. Participation and Elements of the School for Young Scientists (Yekaterinburg, October 29 – November 2, 2018). Yekaterinburg : Alfa Print Publishing House and Printing House, Irkutsk: IRNTU Publishing House, 2018. pp. 382–386.
6. Barkhatov V. I., Dobrovolskiy I. P., Kapkaev Yu. Sh. Wastes of Production and Consumption – a Reserve of Building Materials: Monograph. Chelyabinsk: Izdatelstvo Chelyabinskogo Gosudarstvennogo Universiteta. 2017. 477 p.

7. Nemchinova N. V., Mineev G. G., Tyutrin A. A., Yakovleva A. A. Utilization of Dust from Silicon Production. Steel in Translation. 2017. Vol. 47, Iss. 12. pp. 763–767.
8. Sizyakov V. M., Brichkin V. N. About the Role of Hydrafed Calcium Carboaluminates in Improving the Technology of Complex Processing of Nephelines. Journal of Mining Institute. 2018. Vol. 231. pp. 292–297.
9. Trushko V. L., Utkov V. A., Bazhin V. Y. Topicality and Possibilities for Complete Processing of Red Mud of Aluminous Production. Journal of Mining Institute. 2017. Vol. 227. pp. 547–553.
10. Nemchinova N. V., Leonova M. S., Tyutrin A. A. Experimental Works on Pelletized Charge Smelting in Silicon
Production. Proceedings of Irkutsk State Technical University. 2017. Vol. 21, Iss. 1, pp. 209–217.
11. Ringdalen E., Tangstad M. Reaction Mechanisms in Carbothermic Production of Silicon, Study of Selected Reactions. International Smelting Technology Symposium. 2012. pp. 195–203.
12. Cheremisina O. V., Ponomareva M. A., Bolotov V. А., Osipov A. S., Sitko A. V. Thermodynamic Characteristics of the Hydrogen Sulfide Sorption Process by Ferromanganese Materials. ACS Omega. 2022. Vol. 7, Iss. 3. pp. 3007–3015.
13. Gasik M. I., Gasik M. M. Electrothermia of Silicon. Dnepropetrovsk: Natsionalnaya Metallurgicheskaya Akademiya Ukrainy, 2011. 487 p.
14. Katkov О. М. (ed.). Smelting of Technical Silicon. Irkutsk: Kremniy, 1999. 244 р.
15. Nemchinova N. V. Behavior of Impurity Elements in Silicon Production and Refining: a Monograph. Moscow: Akademiya Estestvennykh Nauk, 2008. 236 p.
16. Lewis R., Fidjestøl R. Microsilica as an Addition. In: Lea’s Chemistry of Cement and Concrete (Fifth Edition). Elsevier, 2017, pp. 509–535. DOI: 10.1016/B978-0-08-100773-0.00011-3
17. Lewis R. The Role of Microsilica in Sustainable Concrete. MATEC Web of Conferences. 2017. Vol. 120. 02011. DOI: 10.1051/matecconf/201712002011.
18. Fidjestøl P., Dåstøl M. The History of Silica Fume in Concretefrom Novelty to Key Ingredient in High Performance Concrete. Elkem Materials, Norway, 2012. URL: http://ibracon.org.br/eventos/50cbc/plenarias/PER_FIDJESTOL.pdf (accessed: 06.06.2022).
19. Munkhtuvshin D., Balabanov V. B., Putsenko K. N. Experience of Use of Adds of Micro- and Nanosilica from the Wastes of Silicone Production in Concrete Technologies. Izvestiya vuzov. Investitsiyi. Stroyitelstvo. Nedvizhimost. 2017. Vol. 7, Iss. 3. pp. 107–115. DOI: 10.21285/2227-2917-2017-3-107-115
20. Smirnova, O. M., Potyomkin D. A. Influence of Ground Granulated Blast Furnace Slag Properties on the Superplasticizers Effect. International Journal of Civil Engineering and Technology. 2018. Vol. 9, Iss. 7. pp. 874–880.
21. Johnson S., Brabie V., Bohlin L. Corrosion mechanism and kinetic behaviour of refractory materials in contact with CaO – Al2O3 – MgO – SiO2 slags. Proceedings of the VII International Conference on Molten Slags Fluxes and Salts. The Southern African Institute of Mining and Metallurgy, Johannesburg. 2004, pp. 341–348.
22. Boenzi F. Possible Ecological Advantages from Use of Carbonless Magnesia Refractory Bricks in Secondary Steelmaking: a Framework LCA Perspective. International Journal of Environmental Science and Technology. 2021, DOI: 10.1007/s13762-021-03553-2.
23. Pashkov E. I., Permyakov M. B., Krasnova T. V. Protection of Heat Engineering Units in an Aggressive High Temperature Environment with Building Heat-Insulating Materials. The Eurasian Scientific Journal. 2021. Vol.13, Iss. 2. URL: https://esj.today/PDF/35SAVN221.pdf (accessed: 06.06.2022).
24. Zubashchenko R. V. Thermal-Resistant High-Temperature Heatinsulating Alumina-Silicate Fiber Products. Novye Ogneupory (New Refractories). 2016. No. 12. pp. 3–5.
25. Andreikovets I. N., Vasiltsov V. S. Modernization of Production in the Conditions of Tough Competition on the Market of Refractories. Journal of Mining Institute. 2013. Vol. 205. pp. 148–150.
26. Marchenko N. V., Vershinina E. P., Hildebrandt E. M. Metallurgy of Heavy Non-ferrous Metals. Krasnoyarsk: IPK SFU, 2009. 394 p.
27. Shapovalov A. N. Theory of Metallurgical Processes: Educational and Methodical Manual. Novotroitsk: NF NITU “MISiS”, 2015. 91 p.
28. Saitov A. V., Bazhin V. Yu., Feshchenko R. Yu. Operational Problems of a Graphitized Cathodic Block Lining in Contemporary Aluminum Electrolyzers. Refractories and Industrial Ceramics. 2017. Vol. 58, Iss. 2. pp. 126–129.
29. Nemchinova N. V., Tyutrin A. A., Somov V. V. Determination of Optimal Fluorine Leaching Parameters from the Coal Part of the Waste Lining of Dismantled Electrolytic Cells for Aluminum Production. Journal of Mining Institute. 2019. Vol. 239. pp. 544–549.
30. Litvinenko V. S. Digital Economy as a Factor in the Technological Development of the Mineral Sector. Natural Resources Research. 2020, Vol. 29, Iss. 3. pp. 1521–1541.
31. Pyagay I. N., Shaidulina A. A., Konoplin R. R., Gorshneva E. A., Sutyaginsky M. A. Production of Amorphous Silicon Dioxide Derived from Aluminum Fluoride Industrial Waste and Consideration of the Possibility of Its Use as Al2O3–SiO2 Catalyst Sup ports. Catalysts. 2022. Vol. 12, Iss. 2. 162. DOI: 10.3390/catal12020162
32. Lapshin V. L., Nemchinova N. V., Salov V. M. Algorithm for Studying the Process of Vibratory Separation of Mineral Raw Materials. Sustainable Development of Mountain Territories. 2020. Vol. 12, Iss. 1. pp. 137–144.
33. Litvinenko V.S., Tsvetkov P.S., Molodtsov K.V. The Social and Market Mechanism of Sustainable Development of Public Companies in The Mineral Resource Sector. Eurasian Mining. 2020. No. 1. pр. 36–41. DOI: 10.17580/em.2020.01.07
34. Gorbunov А. А., Yurovskikh А. S., Evaluation of the Accuracy of the Crystalline Phases Content Determination by Rietveld Refinement. XVII International Scientific and Technical Ural School-Seminar of Metal Scientists-Young Scientists. Yekaterinburg, December 5–9, 2016 : Collection of Scientific Papers (in two parts). Part two. Yekaterinburg : Izdatelstvo Uralskogo universiteta, 2016. pp. 282–286.
35. Onasenko Yu. A., Peschanskaya V. V. High Temperature Processes of Phase Formation in the System “Cement “Gorkal-70” — Microsilica”. Technology Audit and Production Reserves. 2013. Vol. 1, Iss. 2(9). pp. 25–28.
36. Bazhin V. Y., Glaz’ev M. V. Combined Refractory Materials with Addition of Technogenic Waste for Metallurgical Assemblies. Refractories and Industrial Ceramics. 2021. Vol. 61, Iss. 6. pp. 644–648.
37. Glaz’ev M. V., Bazhin V. Y. On the Recycling and Use of Microsilica in the Oil Industry. E3S Web of Conferences. 2021. Vol. 266. 02010. DOI: 10.1051/e3sconf/202126602010

Полный текст статьи Refractory materials of metallurgical furnaces with the addition of silicon production waste
Назад