Журналы →  Chernye Metally →  2024 →  №2 →  Назад

Casting and Foundry Production
Название Increasing the strength properties of lignosulfonates with surfactants
DOI 10.17580/chm.2024.02.05
Автор A. P. Firstov, O. I. Shevchenko
Информация об авторе

Nizhny Tagil Technological Institute (branch) of the Ural Federal University named after the first President of Russia B. N. Yeltsin, Nizhny Tagil, Russia

A. P. Firstov, Cand. Eng., Associate Prof., Dept. of Metallurgical Technologies, e-mail: first55@mail.ru
O. I. Shevchenko, Dr. Eng., Associate Prof., Head of the Dept. of Metallurgical Technologies, e-mail: oleg.shevchenko@urfu.ru

Реферат

Lignosulfonates have found application in foundries. They are a component of foundry glue for production of complex cores, are included in molding and core mixtures, and serve as additives in aqueous clay suspensions for active wetting of sand. In addition, lignosulfonates are binders, but due to their properties they provide insignificant strength to the cores and, according to the accepted classification, are weak binders. To increase the strength properties of manufactured cores, lignosulfonates are used with stronger binders. The use of lignosulfonates as an independent binder is possible when they are modified with sulfonols. In foundry production, sulfonols are used to obtain a uniform molding mixture with a high viscosity of the binder component in order to increase surface activity. To improve the wettability of the filler (as a flotation reagent), it is recommended to introduce various surfactants into the composition of molding and core mixtures. In foundry production, anionic sulfonols are usually used: DS-RAS, Petrov's Contact, black neutralized refined contact (KChNR) and neutralized black contact (NChK). The substances are low and moderately toxic and belong to hazard class 3 (the danger is posed by sulfonol dust, which can penetrate the respiratory system and come into contact with unprotected skin).

Ключевые слова Lignosulfonate, sulfide groups, molecular fraction, petroleum fractions, sulfonol, industrial safety, ecology, strength, viscosity, modification.
Библиографический список

1. Firstov A. P. Influence of functional groups on the molecular structure of lignosulfonates. Youth and Science: Proceedings of the International scientific and practical conference of high schoolers, students and graduate students (May 27, 2022, Nizhny Tagil): in 2 volumes. Vol. 1. Nizhny Tagil : NTI (branch) UrFU. 2022. pp. 232–236.
2. Sarkanen K. V., Ludwig C. H. Lignins. Occurrence, Formation, Structure and Reactions. Translated from English. Moscow : Lesnaya promyshlennost, 1981. 402 p.
3. Azarov V. I., Burov A. V., Obolenskaya A. V. Chemistry of wood and synthetic polymers. Saint Petersburg : LTA, 1999. 627 p.
4. Khabarov Yu. G., Veshnyakov V. A., Kuzyakov N. Yu. Preparation and application of lignosulfonic complexes with iron cations. Izvestiya vuzov. Lesnoy zhurnal. 2019. No. 5. pp. 167–187.
5. Firstov A. P. Modification of lignosulfonates with iron (III) sulfate. Teoriya i tekhnologiya metallurgicheskogo proizvodstva. 2022. No. 2 (41). pp. 18–21.
6. Afanasyev N. I., Teltevskaya S. E. et al. Structure and physicochemical properties of lignosulfonates. Yekaterinburg : UrO RAN, 2005. 166 p.
7. Technical Specification (TU) 13-7308001-670-84. Complex linguistic binder. Specifications. Moscow, 1984. 13 p.
8. Afanasyev N. F., Tseluiko M. K. Additives to concrete and mortars. Kiev : Budivelnyk,1989. 128 p.
9. Ryazanov Ya. A. Handbook on drilling fluids. Orenburg : Letopis, 2005. 664 p.
10. Bulatov A. I., Danyushevsky V. S. Grouting materials: textbook for universities. Moscow : Nedra, 1987. 280 p.
11. Bagregov V. F., Nenartovich L. P. On the composition of Petrov’s contact. Dmitrovgrad : NIIAR, 1973. 11 p.
12. Lebedev N. N. Chemistry and technology of basic organic and petrochemical synthesis : textbook for universities. 4th edition revised and additional. Stereotype edition. Moscow : Alyans, 2016. 592 p.
13. Brovko O. S., Palamarchuk I. A., Makarevich N. A., Boytsova T. A. Polymolecular characteristics of sodium lignosulfonates, chitosan and polyethylenepolyamine. Khimiya rastitelnogo syrya. 2009. No. 1. pp. 29–36.
14. Popova V. L., Shitova T. T., Makarova G. A. New binders based on technical lignosulfonates. Use of wood raw materials: abstracts of reports of the 1st All-Union Conference. Riga, 1984. pp. 64–66.
15. Ternay A. Contemporary organic chemistry. Vol. 2. Translated from English. Moscow : Mir, 1981. 651 p.
16. Bialski A. M., Bradford H., Lewis N. G., Luthe C. E. Lignosulfonate polymerization - effect of crosslinking agents. J. Appl. Polymer Sci. 1986. Vol. 31. pp. 1363–1372.
17. GOST 18995.1–73. Liquid chemical products. Methods for determination of density. Introduced: 01.07.1974.
18. GOST 18995.6–73. Organic chemical products. Methods for determination of boiling point. Introduced: 01.07.1974.
19. GOST 23409.7–78. Molding sands, molding and core sand mixtures. Methods for determination of compressive, tensile, bending and shearing strength. Introduced: 01.01.1980.
20. GOST 12.1.007–76. Noxious substances. Classification and general safety requirements. Introduced: 01.01.1977.
21. Technical Specification (TU) 13-0281036-029-94. Technical lignosulfonates. Specifications. Moscow, 1994. 29 p.
22. Technical Specification (TU) 2455-064-05711131-03. Technical liquid lignosulfonates. Specifications. Moscow, 2004. 9 p.
23. Technical Specification (TU) 2455-028-00279580-2014. Technical liquid and powder lignosulfonates. Moscow, 2014. 12 p.
24. Zakis G. F. Functional analysis of lignins and their derivatives. Riga : Izdatelstvo Zinatne, 1987. 265 p.
25. Sokolov O. M., Babikova N. D., Popova V. L. Determination of the molecular weights of lignosulfonates by the unsteady equilibrium method in an ultracentrifuge. Khimiya drevesiny. 1977. No. 5. pp. 68–72.
26. Brovko O. S., Palamarchuk I. A., Vishnyakova A. P. Effect of molecular weight of lignosulfonate sodium on complexation with polyethylene polyamine. Khimiya rastitelnogo syrya. 2011. No. 1. pp. 65–70.
27. Modrzejewska-Sikorska A., Konował E., Cichy A., Nowicki M. et al. The effect of silver salts and lignosulfonates in the synthesis of lignosulfonate stabilized silver nanoparticles. Journal of Molecular Liquids. 2017. Vol. 240. pp. 80–86.
28. GOST 1532–81. Viscometers of relative viscosity. Specifications. Introduced: 01.01.1982.
29. Bogolitsyn K. G. et al. Physical chemistry of lignin: monograph; edited by K. G. Bogolitsyn, V. V. Lunin. Moscow : Akademkniga, 2010. 492 p.
30. Volchek K., Brown C. E., Velicogna D. Evaluation of sodium lignosulphonate for the remediation of chromium-contaminated soil and water. International Journal of Innovation and Sustainable Development. 2013. Vol. 7, Iss. 3. pp. 289–302.
31. Brovko O. S. et al. Metal-carbon composites based on lignosulfonates. Izvestiya vuzov. Lesnoy zhurnal. 2020. No. 3. pp. 159–169.

Language of full-text русский
Полный текст статьи Получить
Назад