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NANOMATERIALS AND NANOTECHNOLOGY
ArticleName FeNi3/C nanocomposite synthesis from FeCl3·6H2O/NiCl2·6H2O/polyacrylonitrile system by IR heating
ArticleAuthor L. V. Kozhitov, A. V. Kostikova, V. V. Kozlov, V. I. Khursa
ArticleAuthorData L. V. Kozhitov; A. V. Kostikova, MISiS National Research and Technical University; V. V. Kozlov; A. V. Topchev Petrochemical Synthesis Institute, Russian Academy of Sciences; V. I. Khursa, Moscow State Industrial University.
Abstract

The method of obtaining a composite based on FeNi3 nanoparticles in a carbon material from the FeCl3·6H2O/NiCl2·6H2O/polyacrylonitrile system under IR heating has been developed. The possibility of Fe and Ni reduction from FeCl3 and NiCl2 by Н2 evolution from the polymer at temperatures above 300 °С is supported by thermodynamic analysis. The formation of 20 to 60 nm size FeNi3 nanoparticles has been confirmed by X−ray and scanning electron microscopy.
keywords Nanocomposite, synthesis, polyacrylonitrile.
References

1. Gubin, S. P. Magnitnye nanochastitsy: metody polucheniya, stroenie i svoystva / S. P. Gubin, Yu. A. Koksharov, G. B. Khomutov, G. Yu. Yurov // Uspekhi khimii. − 2005. − № 6. − C. 539—574.
2. Sun, S. Size−Controlled Synthesis of Magnetite Nanoparticles / S. Sun, H. Zeng, J. Am // Chem. Soc. − 2002. − N 124. − P. 124—128.
3. Kekalo, I. B. Fizicheskoe materialovedenie pretsizionnykh splavov. Splavy s osobymi magnitnymi svoystvami / I. B. Kekalo, B. A. Samarin. − M. : Metallurgiya, 1989. − 496 s.
4. Kozhitov, L. V. Tekhnologiya materialov mikro− i nanoelektroniki / L. V. Kozhitov, V. G. Kosushkin, V. V. Krapukhin, Yu. N. Parkhomenko. − M. : MISiS, 2007. − 544 s.
5. Magnitomyagkie materialy: Entsiklopedicheskiy slovar'−spravochnik / Yu. Starodubtsev. − M. : Tekhnosfera, 2011. − 664 s.
6. Kozhitov, L. V. Struktura i fiziko−khimicheskie svoystva organicheskogo poluprovodnika na osnove poliakrilonitrila i ego kompozita s nanochastitsami medi / L. V. Kozhitov, V. V. Krapukhin, G. P. Karpacheva, V. V. Kozlov // Izv. vuzov. Materialy elektron. tekhniki. − 2004. − № 4. − C. 7—10.
7. Marangoni, A. Structural basis for the yield stress in plastic disperse systems / A. Marangoni, M. Rogers // Appl. Phys. Lett. − 2003. − V. 82, N 19. − P. 3239.
8. Cavin, R. K. Semiconductor research needs in the nanoscale physical sciences: A semiconductor research corporation working paper / R. K. Cavin, J. C. Daniel, V. V. Zhirnov // J. Nanoparticle Res. − 2000. − V. 2. − P. 213.
9. Bannykh, O. A. Diagrammy sostoyaniya dvoynykh i mnogokomponentnykh sistem na osnove zheleza / O. A. Bannykh, P. B. Budberg, S. P. Alisova. − M. : Metallurgiya, 1986. − 440 s.
10. Kalashnik, A. T. Svoystva i struktura poliakrilonitril'nykh volokon / A. T. Kalashnik, T. N. Smirnova, O. P. Chernova, V. V. Kozlov // Vysokomolekulyarnye soedineniya. − 2010. − № 11. − S. 1—6.
11. Kozlov, V. V. Osobennosti obrazovaniya sistemy polisopryazhennykh svyazey poliakrilonitrila v usloviyakh vakuuma pri termicheskoy obrabotke / V. V. Kozlov, G. P. Karpacheva, V. S. Petrov, E. V. Lazovskaya // Tam zhe. − 2001. − T. 43, № 1. − S. 23—26.
12. Ryabin, V. A. Termodinamicheskie svoystva veshchestv. Spravochnik / V. A. Ryabin, M. A. Ostroumov, T. F. Svit. − M. : Khimiya, 1977. − 392 s.
13. Kozlov, V. V. O khimicheskikh prevrashcheniyakh poliakrilo-nitrila pri termicheskoy obrabotke v vakuume i atmosfere ammiaka / V. V. Kozlov, G. P. Karpacheva, V. S. Petrov, E. V. Lazovskaya, S. A. Pavlov // Izvestiya vuzov. Materialy elektron. tekhniki. − 2004. − № 4. − C. 45—49.
14. Lyakishev, N. P. Diagramma sostoyaniya dvoynykh metallicheskikh sistem / N. P. Lyakishev. − M. : Mashinostroenie, 1996. − 448 s.
15. Ravel', A. A. Kratkiy spravochnik fiziko−khimicheskikh velichin / A. A. Ravel'. − L. : Khimiya, 1983. − 232 s.
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