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MODELING OF PROCESSES AND MATERIALS
ArticleName Thermodynamic peculiarity of vibrational activation of chemical compound melts
ArticleAuthor I. Kh. Avetissov, A. P. Sadovskiy, A. V. Khomykov, S. D. Belov
ArticleAuthorData

Mendeleyev University of Chemical Technology of Russia

I. Kh. Avetissov, A. P. Sadovskiy, A. V. Khomykov, S. D. Belov

Abstract

Direct measurements of complex inorganic compound crystallization showed an increase in the crystallization heat during melt activation by low−frequency vibrations. Phase equilibrium analysis of semiconductor systems using the quaziideal solution model showed that the observed crystallization heat increase could be a result of cluster destruction in the melt.

keywords Inorganic melt crystallization, melt activation, melt associates, melt clusters, low−frequency vibrations
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