Журналы →  Obogashchenie Rud →  2012 →  №5 →  Назад

BENEFICIATION PROCESSES
Название A method of mineral particles magnetic properties selective alteration by colloids
Автор Bragin V. I., Baksheeva I. I.
Информация об авторе

Siberian Federal University; Institute of Chemistry and Chemical Technology, Siberian Branch of RAS (Russia):

Bragin V. I., Head of Chair, Doctor of Engineering, Professor

 

Siberian Federal University (Russia):

Baksheeva I. I., Postgraduate, Irina_igorevna@mail.ru

Реферат

A method of minerals recovery is described, based on magnetic colloids application for mineral particles magnetic properties control with subsequent separation of concentrate by magnetic concentration methods. Information is presented, characterizing magnetic colloids application features in various fields of science and technology. The principles for development of the proposed beneficiation method are substantiated, based on the methods of particles selfassembly and functionalisation that are widely used in nanotechnology, as well as for magnetic nanoparticles control in medicine, in water purification technology and other areas. It was proposed to use magnetic colloids in stabilized aqueous dispersion forms and in solidoilwater double dispersion form. Rational compositions of stabilizing and functionalizing reagents are substantiated with respect to each colloid form. Interaction of functionalized magnetic colloids with surfaces of various compositions was studied by means of scanning electron microscope Hitachi S5500. Selective attachment of colloids, functionalized by sulfhydric reagent, to gold surface was established. It is shown, that aqueous colloid forms structured thin film, and double dispersion — a thicker and more expand ed layer. Magnetic concentration experiments were accomplished with preliminary treatment by functionalized magnetic colloid on the Samsonovskoye ore field gold clay ore, also demonstrating possibility for selection.

Ключевые слова Magnetic separation, gold, magnetic colloid, colloid functionalisation, finely disseminated ores, ores with rebellious gold, man-caused raw materials, nanoparticles
Библиографический список

1. Rosensweig R. E. Ferrogidrodinamika (Ferrohydrodynamics). Transl. from Eng.; under ed. V. V. Gogosov. Moscow, Mir, 1989, pp. 120–240.

2. Taketomi S., Tikadzumi S. Magnitnye zhidkosti  (Magnetic liquids). Transl. from Jap.; under ed. V. Ye. Fertman. Moscow, Mir, 1993, pp. 69–94, 113–122, 125–137.

3. Orlov D. V., Mikhalyov Yu. O, Sizov A. P. Magnitnye zhidkosti v mashinostroyenii (Magnetic liquids in mechanical engineering). Moscow, Mashinostroyeniye, 1993, pp. 6–41, 166–242.

4. Fertman V. Ye. Magnitnye zhidkosti (Magnetic liquids). Minsk, Vysshaya Shkola, 1988, pp. 9–44, 104–162.

5. Shliomis M. I. Uspekhi fizicheskikh nauk — Physics,Uspekhi, 1974, No. 112, iss. 3, pp. 3–9.

6. Pankhurst Q. A., Connolly J., Jones S. K., Dobson J. Applications of magnetic nanoparticles in biomedicine. J. of Physics D: Applied Physics, 2003, 36, pp. R167–R181.

7. Arruebo M., Fernandez-Pacheco R., Irusta S. et al. Sustained release of doxorubicin from zeolite-magnetite nanocomposites prepared by mechanical activation. Nanotechnology, 2006, Vol. 17, pp. 4057–4064.

8. Widder K. J., Senyei A. E., Scarpelli D. G. Proc. of The Society for Experimental Biology and Medicine, 1978, No. 58, pp. 141–146.

9. Widder K. J., Senyei A. E., Czerlinski G. J. of Applied Physics, 1978, Vol. 49, No. 6, pp. 3578–3583.

10. Widder K. J., Morris R. M., Poore G. Proc. of the National Academy of Sciences USA, 1981, Vol. 78, No. 1, pp. 579–581.

11. Widder K. J., Morris R. M., Poore G. Eur. J. Cancer Clin. Oncol, 1983, Vol. 39, No. 1–2, pp. 135–139.

12. Yean S., Cong L., Yavuz C. T., Mayo J. T., Yu W. W., Kan A. T., Colvin V. L., Tomson M. B. Effect of magnetite particle size on adsorption and desorption of arsenite and arsenate. J. of Materials Research, 2005, 20 (12), pp. 3255–3264.

13. Pat. No. 2,232,294 U. S. Urbain, Stemen W. R., Feb. 18, 1941.

14. Bolto B. A., Dixon D. R., Eldridge R. J., Swinton E. A., Weiss D. E., Willis D., Battaerd H. A. J., Young P. H. J. of Polymer Science, Polymer Symp., 1975, No. 49, p. 211.

15. Bolto B. A., Dixon D. R., Eldridge R. J., Kolarik L. O., Priestley A. J., Raper W. G. C., Rowney J. E., Swinton E. A., Weiss D. E. The theory and practice of ion exchange. Soc. Chem. Ind. London, 1976, p. 271.

16. Kolarik L. O., Priestley A. J., Weiss D. E. Proc. 7th Federal Convention of Australian Water and Wastewater Association, Canberra, 21–24 Sept. 1977.

17. Pat. No. 512,553 Aust., Pat. No. 1,583,881 U. K. Weiss D. E., Kolarik L. O., Priestley A. J.

18. Pat. No. 518,159 Aust., Pat. No. 4,279,756 and 4,363,749 U. S. Kolarik L. O., Anderson N. J., Weiss D. E., Priestley A. J.

19. Zborowski M., Chalmers J. J. Magnetic cell separation. Elsevier, 2008.

20. Pat. 4,430,239 USA, ISM H01F 10/10, Ferrofluid composition. Wyman J. E. (USA).

21. Ivanov M. R., Bednar H. R., Haes A. J. Investigations of the mechanism of gold nanoparticle stability and surface functionalization in capillary electrophoresis. ACS Nano, 2009, 3 (2), pp. 386–394.

22. Volkert A. A., Subramaniam V., Ivanov M. R., Goodman A. M., Haes A. J. Salt-mediated self assembly of thioctic acid on gold nanoparticles. ACS Nano, 2011, 5(6), pp. 4570–4580.

23. Oh E., Delehanty J. B., Sapsford K. E., Susumu K., Goswami R., Blanco-Canosa J. B., Dawson P. E., Granek J., Shoff M., Zhang Q., Goering P. L., Huston A., Medintz I. L. Cellular uptake and fate of PEGylated gold nanoparticles is dependent on both cell-penetration peptides and particle size. ACS Nano, 2011, 5(8), pp. 6434–6448.

24. Liebert T., Hussain M. A., Tahir M. N. Synthesis and characterization of cellulose α-lipoates: A novel material for adsorption onto gold. Th. Heinze Polymer Bulletin, 2006, 57, pp. 857–863.

25. Rooth M., Shaw A. M. Ph-controlled formation kinetics of self-assembled layers of thioctic acid on gold nanoparticles. J. of Physical Chemistry C, 2007, 111(42), pp. 15363–15369.

26. Elmore W. C. Phys. Rew., 1938, Vol. 54, p. 309.

Language of full-text русский
Полный текст статьи Получить
Назад